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                Poly(Iso-Butylene)聚异「丁烯标准品CAS9003-27-4

                Poly(Iso-Butylene)聚异丁烯标准品CAS9003-27-4
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                • Poly(Iso-Butylene)聚异丁烯标准品CAS9003-27-4
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                APSC
                PIB (进口原装标准⌒品)
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                详细说明
                Poly(Iso-Butylene)聚异丁烯标准品CAS9003-27-4 有机凝胶色谱标准品(Organic GPC/SEC Standards)
                (1)低分子量 聚异丁烯
                Low Mw Poly(Iso-Butylene)
                Catalog # Mp Mw Mn
                PIB114 114 114 114
                PIB226 226 226 226
                PIB300 297 315 289
                PIB320 320 341 314
                PIB345 343 365 334
                PIB400 460 475 435
                PIB500 497 546 503
                PIB565 587 624 562
                PIB665 664 669 601
                PIB720 720 900 675
                PIB780 783 745 665
                PIB840 840 776 675
                PIB890 898 1,028 827
                PIB960 960 950 833
                PIB990 989 1,057 948
                PIB1200 1,236 1,213 1,122
                PIB1300 1,309 1,319 1,237
                PIB1450 1,454 1,362 1,440
                a & K values for Mw 1,000 & Above
                (a = 0.661; K = 0.000197)
                250mg包装
                (2)中等▼分子量 聚异丁烯
                Medium Mw Poly(Iso-Butylene)
                Catalog # Mp Mw Mn
                PIB6000 6,000 6700 5,400
                PIB7600 7,600 8,100 6,700
                PIB8100 8,100 10,000 5,400
                PIB9000 9,000 9,900 7,500
                PIB10000 10,100 10,800 8,700
                PIB14K 14,500 15,700 12,000
                PIB21K 21,400 20,900 13,900
                PIB33K 32,200 33,800 30,000
                PIB37K 37,600 47,400 34,200
                PIB51K 51,300 63,700 43,500
                PIB79K 79,500 92,300 65,500
                PIB85K 87,600 87,000 72,100
                250mg包装
                (3)高分子量 聚异丁烯
                High Mw Poly(Iso-Butylene)
                Catalog # Mp Mw Mn
                PIB90K 90,200 107,000 72,300
                PIB95K 95,400 102,300 76,500
                PIB100K 100,200 117,100 78,100
                PIB108K 105,000 131,900 82,900
                PIB115K 112,300 126,300 88,500
                PIB135K 133,000 140,000 117,000
                PIB150K 147,700 177,900 118,200
                PIB168K 168,400 204,700 130,200
                PIB205K 205,000 256,600 164,000
                PIB256K 256,500 286,000 218,800
                PIB266K 266,000 293,800 240,800
                PIB367K 367,500 412,000 303,500
                PIB400K 398,800 476,300 301,100
                250mg包装
                (4)超高分子量 聚异丁烯
                Ultra High Mw Poly(Iso-Butylene)
                Catalog # Mp Mw Mn
                PIB570K 570,000 721,900 410,200
                PIB820K 820,000 912,000 645,000
                PIB925K 923,500 1,165,000 710,600
                PIB959K 959,500 1,155,000 653,500
                PIB1000K 1,020,000 1,110,000 710,600
                PIB1265K 1,265,000 1,330,000 860,500
                PIB1334K 1,334,000 1,565,000 971,200
                PIB1430K 1,430,000 1,600,000 1,235,000
                PIB1500K 1,500,000 1,580,000 950,000
                PIB2000K 2,000,000 2,170,000 1,685,000
                PIB2100K 2,100,000 2,350,000 1,403,000
                PIB2300K 2,308,000 2,574,000 1,540,000
                PIB2438K 2,438,000 2,700,000 1,318,000
                PIB2600K 2,600,000 2,990,000 2,050,000
                250mg包装
                (5)宽分子量分布 聚异丁烯
                Broad MWD Poly(Iso-Butylene)
                Catalog # Mw Mn Mz IV*
                PIB1400K 1,736,000 992,000 2,810,000 2.354
                PIB1300K 1,309,000 485,400 2,850,000 2.785
                PIB105K 105,000 59,200 196,000 0.495
                PIB80K 79,800 30,000 162,700 0.365
                PIB75K 76,200 21,900 181,700 0.353
                PIB10K 9,700 2,500 20,700 0.099
                PIB6K 7,200 2,050 12,800 0.085
                PIB3K 2,750 1,300 4,800 0.061
                PIB1K 1,600 950 3,600 0.043
                1.0g包装

                注解:

                Mn Number average molecular weight

                Mp Peak average molecular weight

                Mv Viscosity average molecular weight

                Mw Weight average molecular weight

                Mz Z-average molecular weight

                IV* Intrinsic Viscosity (dl/gm)

                数均分子量(Number-average molecular weight):按聚合物中含有的分子数目统计平均的分子量,高分子样品中所有分子的总重量除以其分子(摩尔)总数。

                重均分子量( Weight-average molecular weight):按照聚合物的重量进行统计平均的分子量,i-聚体的分子量乘以其重量分数的加和。

                Z均分子量(Z-average molecular weight ):按照Z值统计平均的分子量

                粘均分子量(Viscosity- average molecular weight):对于一定的聚合物-溶剂体系,其特性粘▆数[η]不同。

                Mz > Mw > Mv > Mn,Mv略低于Mw

                Mn靠近聚合物中低分子量的部分,即低分子量部分ㄨ对Mn影响较大

                Mw靠近聚合物中高分子量的部分,即高分子量部分对Mw影响较大

                一般用Mw来表征聚合物♂比Mn更恰当,因为聚合物的性能如强度、熔体粘度更多地依赖于样品中较大的分子。


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